in neat (no solvent)
react. of PCl5 with SO3 vapor; formation of SO2Cl2 and adduct SO2ClO-PCl3-OClO2S; decompn. of SO2Cl2 forming SO2 and Cl2, decompn. of adduct forming a small amount of S2O5Cl2;;
参考文献
Oddo, G.; Sconza, A.
Gazzetta Chimica Italiana, 1927 , vol. 57, p. 83 - 103
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Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in neat (no solvent)
slow reaction in the cold; reaction with detonation in a melting tube at 100 °C;; isolation of S2O5Cl2 and HSO3Cl by distillation of the reaction product; further formation of a white substance (SiO2 and highmolecular Si oxide chlorides) by heating in a vac. for a longer period of time;;
参考文献
Besson, A.; Fournier, L.
c. r., 1909 , vol. 148, p. 1192 - 1194
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Gmelin Handbook: Si: MVol.B, 258, page 701 - 703
Siddiqi, Z. A.; Ansari, N. A.; Aslam, M.; Lutfullah; Zaidi, S. A. A.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1981 , vol. 20, # 1 p. 30 - 32
in neat (no solvent)
Irradiation (UV/VIS); mixt. of Cl2, SO2 and O2 irradiated (>320 nm) at -78°C; distd. into traps (-90, -120, -196°C); O2 pumped off; distd. intotraps (-70, -110, -196°C) by slow warming to room temp.; peroxid e from -70°C trap purified by trap-to-trap distns.; collected in -50°C trap; detd. by IR, Raman;
参考文献
Romano, Rosana M.; Vedova, Carlos O.Della; Beckers, Helmut; Willner, Helge
Inorganic Chemistry, 2009 , vol. 48, # 5 p. 1906 - 1910
