1H,1H,1H,3H,3H-全氟-2-壬酮 合成路线 (共 7 条)
→
反应条件
75824-01-0 5,5,6,6,7,7,8,8,9,9,9-Undeca氟壬烷-2,4-二酮
反应条件
1: 82 percent / NH3 / diethyl ether / 1 h / Ambient temperature 2: 78 percent / aq. HCl / 1 h / Heating View Scheme
参考文献
Huang, Wei-yuan; Wu, Yong-ming
Journal of Fluorine Chemistry, 1992 , vol. 59, # 2 p. 179 - 183
反应条件
chromium(VI) oxide; sulfuric acid in acetone
3 h; Ambient temperature;
参考文献
Moreau,P.; Naji,N.
Journal of Fluorine Chemistry, 1987 , vol. 34, p. 421
反应条件
sodium dithionite; sodium hydrogencarbonate in water; acetonitrile
T=40°C;
参考文献
Huang, Wei-yuan; Wu, Yong-ming
Journal of Fluorine Chemistry, 1992 , vol. 59, # 2 p. 179 - 183
反应条件
potassium hydroxide in acetone
electrolysis;
参考文献
Vol'pin, I. M.; Kurykin, M. A.; Grinberg, V. A.; Vasil'ev, Yu. B.; German, L. S.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 7 p. 1395 - 1400
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 7 p. 1578 - 1584
反应条件
1: 95 percent / 1) LiAlH4 / diethyl ether / 10 h / Heating
2: 87 percent / CrO3, conc. H2SO4 / acetone / 3 h / Ambient temperature
View Scheme
参考文献
Moreau,P.; Naji,N.
Journal of Fluorine Chemistry, 1987 , vol. 34, p. 421
反应条件
2,2'-azo-bisisobutyronitrile; acide sulfurique; N-ethyl-N,N-diisopropylamine
1.) pentane, 100 deg C, heating in autoclave, 6 h; 2.) water, 16 h;
参考文献
Molines, Huguette; Tordeux, Marc; Wakselman, Claude
Bulletin de la Societe Chimique de France, 1982 , vol. 2, # 11-12 p. 367 - 368
反应条件
electrolysis, platinum or glasscarbon electrodes; Yield given;
参考文献
Vol'pin, I. M.; Kurykin, M. A.; Grinberg, V. A.; German, L. S.
Journal of Fluorine Chemistry, 1991 , vol. 54, # 1-3 p. 303