in gaseous matrix Kinetics; Irradiation (UV/VIS); temp. range 296 - 670 K, pressure 100 and 300 Torr, Ar as buffer gas; resistively heated pyrex cross;
in solid matrix Irradiation (UV/VIS); Hg evapd. from liq. at 50°C; codeposited with D2 (2-8percent) and O2 (0.2-2.0percent) in excess Ne onto CsI window at 5 K for 1 h; irradiated (mercury arc, > 220 nm) for 25 min; annealed to 12 K; monitored by IR spectra;
in neat (no solvent) Kinetics; react. of H2-D2 over PMo12 at 573 K; initial pressures of H2: 12 Torr, D2 20 Torr; detn. of pressure decrease; evolved water detd. volumetrically;
参考文献
Journal of Physical Chemistry, , vol. 94, # 2 p. 890 - 894
