in dichloromethane AgClO4 added to soln. of Ru-complex, stirred for 10 min in absence of light; mixt. filtered, solvent evapd. (vac.), recrystd. from CH2Cl2/diethyl ether; elem. anal., detd. by XRD;
参考文献
Angewandte Chemie - International Edition, , vol. 42, # 39 p. 4767 - 4771
in water byproducts: H2O; heating powdered Ag with HClO3 in presence of HCl traces for 2 hours; solution of 44 percent of Ag, formation of AgCl from 8.75 percent of Ag;;
参考文献
Journal of the American Chemical Society, , vol. 25, p. 637 - 641
in water addition of equimolar amounts of AgNO3 and NaClO3 in H2O and heating at 85°C;; cooling down and washing the precipitate with ice water; formation of 95.2 percent AgClO3 (yield: 78.5 percent); repeated recrystallization from water with formation of 99.7 percent AgClO3 (yield 62 percent);;
in water byproducts: AgCl; introduction of Cl2 into a suspension of Ag2O in H2O under shaking and heating to 60°C;; crystallization on evaporating;;
参考文献
Ag: MVol.B1, 6.14.1.3, page 499 - 500
Untersuchungen ueber die Gesetze der chemischen Proportionen, ueber die Atomgewichte und ihre gegenseitigen Verhaeltnisse, Leipzig 1867, S. 91/105, uebersetzt von Aronstein, L.
