WF5 placing in ampoule with vac. tap, evac., placing in thermostat (298 K for 25, 50, 75 and 100 h), WF6 distn. at the interval end; gravimetric monitoring;
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 22, p. 6 - 8
Zhurnal Neorganicheskoi Khimii, , vol. 22, p. 14 - 17
Timakov, A. A.; Prusakov, V. N.; Drobyshevskii, Yu. V.
Kinetics and Catalysis, 1982 , vol. 23, p. 889 - 892
Kinetika i Kataliz, 1982 , vol. 23, p. 1048 - 1051
Walker; Winfield
Journal of Inorganic and Nuclear Chemistry, 1972 , vol. 34, p. 759
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Gmelin Handbook: B: B-Verb.13, 2.3.3, page 91 - 93
in hydrogen fluoride HF (liquid); (N2); distillation of HF to Sb2S3, addn. of WF6 at -196°C, warming to room temp., storage for 16 h (or 14 h); decantation and soln. cooling to -78°C, extn. (HF) from solid, washing of solid at room temp., decantation, evapn. under vacuum at -78°C, drying for 10 min at room temp.;
参考文献
Nieboer, Jared; Hillary, William; Yu, Xin; Mercier, Helene P. A.; Gerken, Michael
Inorganic Chemistry, 2009 , vol. 48, # 23 p. 11251 - 11258
in neat (no solvent) Kinetics; byproducts: WF5(1-), SiF, WF4(1-); 25°C, pressure of WF6: (0.6-0.3)E-6 Torr; further byproducts: SiF(1-), WF5, SiF2; not isolated, detd. by FTMS;
参考文献
Reents, W. D. Jr.; Mandich, M. L.; Bondybey, V. E.
Chemical Physics Letters, 1986 , vol. 131, p. 1 - 7
