trifluorophosphane合成路线 （共 187 条）
反应条件
in neat (no solvent)
treating (Ni(CO)4) for 100 h with PF3 at 40 °C;;
参考文献
Chatt, J.; Williams, A. A.
Journal of the Chemical Society, 1951 , p. 3061 - 3067
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Gmelin Handbook: Ni: MVol.C1, 3, page 11 - 13
反应条件
in neat (no solvent)
passing an equimolar mixt. of PCl3 and PF3 through a glass tube containing porcelain pieces heated with an electric furnace; temp. of the formed gases 200 °C;; 50 percent of the mixt. are caused to react;;
参考文献
Gmelin Handbook: P: MVol.C, 184, page 424 - 427
反应条件
in neat (no solvent, gas phase)
react. in a pulsed ion cyclotron resonance spectrometer at 25°C; not isolated, detected by double resonance expt.;
参考文献
Larson, J. W.; Szulejko, J. E.; McMahon, T. B.
Journal of the American Chemical Society, 1988 , vol. 110, # 23 p. 7604 - 7609
反应条件
in gas
Kinetics; room temp., 7 min - 3 h; not isolated, reaction followed by IR spectroscopy;
参考文献
Chen, Grace S. H.; Passmore, Jack
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1251 - 1256
反应条件
-30°C, in vac. apparatus of nickel or stainless steel;
参考文献
Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.9, page 243 - 251
反应条件
in solid matrix
byproducts: S[PF3](n); Irradiation (UV/VIS); photolysis of solid matrix Ar:OCS:PF3=100:1:1 using unfiltered emissionof Hg arc for 55 min at 20 K; with or without annealing matrix to 38 K for 10 min;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334
反应条件
water in not given
react. of PF3 with H2O at ambient temp.;;
参考文献
Hoffman, C. J.; Lutton, J. M.; Parry, R. W.
Bailar, J. C., Inorganic syntheses, Bd. 4, New York-London 1953, S. 149/50
