trifluorophosphane合成路线 （共 187 条）
反应条件
in neat (no solvent)
byproducts: N2; condensing PF3 and NOCl in evacuated trap, -196°C; allowing to attain room temp.; reacting at 25, 65 or 88°C, 1-2 d; detn. by IR;
参考文献
Kalbandkeri, R. G.; Padma, D. K.; Murthy, A. R. Vasudeva
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1981 , vol. 20, p. 83 - 84
反应条件
in neat (no solvent, gas phase)
laser ablated Th was reacted with PF3 in Ar and Ne during condensation at 5 K; IR monitoring;
参考文献
Wang, Xuefeng; Andrews, Lester
Dalton Transactions, 2009 , # 42 p. 9260 - 9265
反应条件
in neat (no solvent)
react. at >100°C and 50-100 atm in a pressure pipe;;
参考文献
Wilkinson, G.
Am. Chem. Soc., 1951 , vol. 73, p. 5501 - 5502
Full Text View citing articles Show Details
Gmelin Handbook: Ni: MVol.C1, 3, page 11 - 13
Full Text Show Details
Wilkinson, G.
N. S. A., NP-1857 (1951) 1/173 1951 , vol. 5, p. 4093
反应条件
in neat (no solvent)
参考文献
Clark, R. J.; Brimm, E. O.
Inorganic Chemistry, 1965 , vol. 4, p. 651 - 654
反应条件
in neat (no solvent)
29percent excess PF3 condensed onto Ni(allyl)2 and reagents allowed to react at 25°C for 1.5 h; react. mixt. fractionated, Ni(PF3)4 recovered in -80°C trap;
参考文献
Severson, Sarah J.; Cymbaluk, Teddy H.; Ernst, Richard D.; Higashi, John M.; Parry, Robert W.
Inorganic Chemistry, 1983 , vol. 22, p. 3833 - 3834
反应条件
in neat (no solvent)
react. at >100°C and 50-100 atm in a pressure pipe;;
参考文献
Gmelin Handbook: P: MVol.C, 171, page 393 - 395
反应条件
in neat (no solvent)
High Pressure; treating Ni-powder (prepd. by thermal decompn. of Ni-oxalate in N2- or H2-stream) in rotary autoclave (Cu-impeller) with PF3 (350 atm) for 42 h at 100 °C;; distilling off PF3 at -100 °C, further react. with PF3 for 16 h at 100 °C and 180 atm;;
参考文献
Gmelin Handbook: Ni: MVol.C1, 3, page 11 - 13
反应条件
in neat (no solvent)
byproducts: PCl3; heating (Ni(PCl3)4) with excess of PF3 in closed tube for 24 h on steam bath, cooling react. tube with liq. N2 after the react. is finished and distilling off PF3 at -115 °C (vac.), raising temp. to 0 °C;; sepg. upper layer of PCl3 from (Ni(PF3)4), fractional distillation in high vac. with addn. of SbF3 and traces of SbF5;;
参考文献
Wilkinson, G.
Am. Chem. Soc., 1951 , vol. 73, p. 5501 - 5502
Full Text View citing articles Show Details
Gmelin Handbook: Ni: MVol.C1, 3, page 11 - 13
Full Text Show Details
Wilkinson, G.
N. S. A., NP-1857 (1951) 1/173 1951 , vol. 5, p. 4093
反应条件
in neat (no solvent)
heating Ni(C5H5)2 and PF3 for several days in closed tube to 65 °C;;
参考文献
Gmelin Handbook: Ni: MVol.C1, 3, page 11 - 13
反应条件
in neat (no solvent)
at higher temp.;;
参考文献
Bigorgne, M.; Zelwer, A.
Bulletin de la Societe Chimique de France, 1960 , p. 1986 - 2002
Full Text Show Details
Gmelin Handbook: Ni: MVol.B3, 23, page 815 - 817
