trifluorophosphane合成路线 （共 187 条）
反应条件
in neat (no solvent)
byproducts: SiF4; heating PSCl3 with AsF3 in a sealing tube at 150 °C; formation of SiF4 by react. with glass of the vessel;;
参考文献
Thorpe, T. E.; Rodger, J. W.
Journal of the Chemical Society, 1888 , vol. 53, p. 766 - 767
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Thorpe, T. E.; Rodger, J. W.
Journal of the Chemical Society, 1889 , vol. 55, p. 306 - 323
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Gmelin Handbook: P: MVol.C, 257, page 588 - 590
反应条件
water
byproducts: HF;
参考文献
Gombler, W.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1978 , vol. 439, p. 207 - 211
反应条件
water
byproducts: HF;
参考文献
Gombler, W.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1978 , vol. 439, p. 207 - 211
反应条件
in neat (no solvent)
expanding excess of NH3 into PClF2, standing for 3 min; removal of volatiles, fractional low-temp. distn. (vac., trap at 227 K);mass spectroscopy;
参考文献
Arnold, David E. J.; Rankin, David W. H.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976 , p. 1130 - 1134
反应条件
in tetrahydrofuran
under inert atmosphere, equimolar amt. of PF2Cl was reacted with L-Selectride in THF at temperature from -100 to -90°C; product contained other unidentified PF2-containing species;
参考文献
Snow, Sarah S.; Jiang, De-Xiang; Parry, Robert W.
Inorganic Chemistry, 1985 , vol. 24, p. 1460 - 1463
反应条件
in tetrahydrofuran
under inert atmosphere, equimolar amt. of PF2Cl was reacted with N-Selectride in THF at temperature from -100 to -90°C; product contained other unidentified PF2-containing species;
参考文献
Snow, Sarah S.; Jiang, De-Xiang; Parry, Robert W.
Inorganic Chemistry, 1985 , vol. 24, p. 1460 - 1463
反应条件
in neat (no solvent)
byproducts: Sn-chloride; react. at 100 °C;;
参考文献
Poulenc, C.
Ann. Chim. Phys., 1891 , vol. 24, p. 548 - 570
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Poulenc, C.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 75 - 78
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Gmelin Handbook: P: MVol.C, 211, page 484 - 487
反应条件
in not given
byproducts: NO(PF6); react. pf PCl3 with NOSO2F;;
参考文献
Seel, F.; Massat, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1955 , vol. 280, p. 186 - 196
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Gmelin Handbook: P: MVol.C, 169, page 388 - 391
反应条件
in neat (no solvent)
decompn. by electric spark;;
参考文献
Moissan, H.
C. r. Acad. Sci. (Paris), 1886 , vol. 103, p. 1257 - 1260
反应条件
in not given
react. with SbCl4F;;
参考文献
Kolditz, L.
Z. anorg. allg. Chem., 1957 , vol. 289, p. 128 - 140
