air; iron(III) sulfate pentahydrate in water H2S and air were bubbled into soln. Fe2(SO4)3*5H2O in N-methylpyrrolidinone-H2O (95:5) at room temp. for 14 h;
air; iron(III) sulfate pentahydrate in water H2S and air were bubbled into soln. Fe2(SO4)3*5H2O in N-methylpyrrolidinone-H2O (95:5) at room temp. for 80.5 h;
air; Iron (III) nitrate nonahydrate in water H2S and air were bubbled into soln. Fe(NO3)3*9H2O in N-methylpyrrolidinone-H2O (95:5) at room temp. for 10.5 at pH = 1;
in neat (no solvent) byproducts: H2O; investigation of partial pressure of equilibrium gas mixture (equimolar amounts H2S and SO2) between 450 and 800°C;; remarkable contents of S6 and S8 obtained;;
参考文献
Journal of the American Chemical Society, , vol. 40, p. 368 - 375
in neat (no solvent) Kinetics; byproducts: H2O; mixture of pure, dry gases (SO2:H2S = 1:2) at 21°C partial pressures 44.8 and 89.6 Torr, investigation of pressure at 308°C, quartz vessel, no acceleration by glass wool;;
Dokiya, M.; Fukuda, K.; Yokokawa, H.; Kameyama, T.
Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 150 - 153
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Gmelin Handbook: S: SVol.4a/b, 1.3.10.1.6, page 264 - 266
