1,2,3,3,4,5,6,6-八氟-1,4-环己二烯合成路线 (共 34 条)
反应条件
vanadium(V) fluoride in monofluoro-trichloromethane T=25°C; 0.416667 h; closed tube;
参考文献
Bardin, V. V.; Avramenko, A. A.; Furin, G. G.; Krasilnikov, V. A.; Karelin, A. I.; et al.
Journal of Fluorine Chemistry, 1990 , vol. 49, # 3 p. 385 - 400
反应条件
potassium permanganate
参考文献
Evans; Tatlow
Journal of the Chemical Society, 1954 , p. 3779,3780
Journal of the Chemical Society, 1955 , p. 1184,1185, 1187
反应条件
nickel T=630 - 660°C;
参考文献
Gething et al.
Nature (London, United Kingdom), 1959 , vol. 183, p. 588
反应条件
(i) SbF5, (ii) SO2; Multistep reaction;
参考文献
Pozdnyakovich,Yu.V.; Shteingarts,V.D.
Zhurnal Organicheskoi Khimii, 1977 , vol. 13, # 9 p. 1911 - 1917,1772 - 1777
反应条件
XeF(1+)*SbF6(1-) in ClSO2F (sulfuryl chloride fluoride); hydrogen fluoride
T=-80 - -70°C; 0.5 h; other temperatures and fluorinating agents; Product distributionMechanism;
参考文献
Bardin, V. V.; Furin, G. G.; Yakobson, G. G.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 525 - 530
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 3 p. 604 - 609
反应条件
bromine trifluoride; SbF5 in ClSO2F (sulfuryl chloride fluoride)
T=-90 - -80°C; 0.5 h;
参考文献
Bardin,V.V.; Furin,G.G.
Journal of Fluorine Chemistry, 1983 , vol. 23, p. 67
反应条件
ClF2(antimony hexafluoride) in ClSO2F (sulfuryl chloride fluoride); hydrogen fluoride
T=-80 - -70°C; 0.5 h;
参考文献
Bardin,V.V.; Furin,G.G.
Journal of Fluorine Chemistry, 1983 , vol. 23, p. 67
反应条件
potassium fluoride in sulfolane
T=50°C; 3 h;
参考文献
Fokin, A. V.; Rapkin, A. I.; Krotovich, I. N.; Valiev, R. Sh.; Studnev, Yu. N.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1987 , vol. 36, # 2 p. 334 - 338
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987 , # 2 p. 375 - 379
反应条件
cesium fluoride in hydrogen fluoride
参考文献
Richardson, T. J.; Tanzella, F. L.; Bartlett, Neil
Journal of the American Chemical Society, 1986 , vol. 108, # 16 p. 4937 - 4943
反应条件
bromine trifluoride; boron trifluoride in ClSO2F (sulfuryl chloride fluoride)
T=-90 - -80°C; 0.333333 h; Title compound not separated from byproducts;
参考文献
Bardin, V. V.; Furin G. G.; Yakobson, G. G.
Journal of Organic Chemistry USSR (English Translation), 1981 , p. 879 - 884
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 5 p. 999 - 1004