DL-3,4-二羟基扁桃酸合成路线 （共 9 条）
反应条件
1: benzene-1,2-diol With aluminum oxide; sodium hydroxide in water 0.0833333 h; 2: formyl formic acid in water T=55°C; 24 h; 3: With sulfuric acid; water T=10°C; pH=1.8; Product distribution / selectivity;
参考文献
DSM IP ASSETS B.V.
Patent: WO2007/9590 A1, 2007 ;
Location in patent: Page/Page column 8 ;
参考文献
Journal of the Chemical Society, , vol. 95, p. 557
反应条件
1: CuCl2·2H2O / ethyl acetate; water / 5 h / 60 °C / |Inert atmosphere 2: sodium hydroxide / water; dichloromethane / 1.58 h / 55 - 60 °C View Scheme
参考文献
Bjorsvik, Hans-Rene; Liguori, Lucia; Minisci, Francesco
Organic Process Research and Development, 2000 , vol. 4, # 6 p. 534 - 543
反应条件
oxygen; acetic acid; bismuth in water; dimethyl sulfoxide T=125°C; P=760.051 Torr; 1 h;
参考文献
Favier, Isabel; Giulieri, Francoise; Dunach, Elisabet; Hebrault, Dominique; Desmurs, Jean-Roger
European Journal of Organic Chemistry, 2002 , # 12 p. 1984 - 1988
反应条件
1: CuCl2·2H2O / ethyl acetate; water / 5 h / 60 °C / |Inert atmosphere 2: sodium hydroxide; tetrabutylammomium bromide View Scheme
参考文献
Bjorsvik, Hans-Rene; Liguori, Lucia; Minisci, Francesco
Organic Process Research and Development, 2000 , vol. 4, # 6 p. 534 - 543
反应条件
1: CuCl2·2H2O / ethyl acetate; water / 5 h / 60 °C / |Inert atmosphere 2: sodium hydroxide / water; dichloromethane / 1.58 h / 55 - 60 °C View Scheme
参考文献
Bjorsvik, Hans-Rene; Liguori, Lucia; Minisci, Francesco
Organic Process Research and Development, 2000 , vol. 4, # 6 p. 534 - 543
反应条件
oxygen; acetic acid; bismuth in water; dimethyl sulfoxide T=125°C; P=760.051 Torr; 1 h;
参考文献
Favier, Isabel; Giulieri, Francoise; Dunach, Elisabet; Hebrault, Dominique; Desmurs, Jean-Roger
European Journal of Organic Chemistry, 2002 , # 12 p. 1984 - 1988
反应条件
CuCl2·2H2O in water; ethyl acetate T=60°C; 5 h; Inert atmosphere;
参考文献
Bjorsvik, Hans-Rene; Liguori, Lucia; Minisci, Francesco
Organic Process Research and Development, 2000 , vol. 4, # 6 p. 534 - 543
反应条件
hydrogenchloride; hydrogen; 5 ruthenium on carbon in water T=55°C; P=18751.9 Torr; 26 h; Product distribution / selectivity;
参考文献
DSM IP ASSETS B.V.
Patent: WO2007/9590 A1, 2007 ;
Location in patent: Page/Page column 3 ;
