1,1,4,4,7,7,10,10-八甲基-2,3,4,7,8,9,10,12-八氢-1H-二苯并[b,h]芴合成路线 （共 4 条）
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77308-48-61,1,4,4,7,7,10,10-八甲基-2,3,4,7,8,9,10,12-八氢-1H-二苯并[b,h]芴
反应条件
1: With AlCl3, aluminium chloride in dichloromethane
T=-8 - 20°C; 22.1667 h;
2: With sodium hydrogencarbonate in water
参考文献
Mitsui Chemicals, Inc.
Patent: EP1548018 A1, 2005 ;
Location in patent: Page/Page column 28 ;
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77308-48-61,1,4,4,7,7,10,10-八甲基-2,3,4,7,8,9,10,12-八氢-1H-二苯并[b,h]芴
反应条件
aluminium trichloride in nitromethane
19 h;
参考文献
Irwin, Levi J.; Reibenspies, Joseph H.; Miller, Stephen A.
Journal of the American Chemical Society, 2004 , vol. 126, # 51 p. 16716 - 16717
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77308-48-61,1,4,4,7,7,10,10-八甲基-2,3,4,7,8,9,10,12-八氢-1H-二苯并[b,h]芴
反应条件
1: 89.4 percent / aq. HCl / 72 h
2: 88.6 percent / AlCl3 / nitromethane / 19 h
View Scheme
参考文献
Irwin, Levi J.; Reibenspies, Joseph H.; Miller, Stephen A.
Journal of the American Chemical Society, 2004 , vol. 126, # 51 p. 16716 - 16717
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77308-48-61,1,4,4,7,7,10,10-八甲基-2,3,4,7,8,9,10,12-八氢-1H-二苯并[b,h]芴
反应条件
aluminium trichloride in dichloromethane
0 deg C, 2 h, then rt, 24 h; Yield given. Yields of byproduct given;
参考文献
Guilhemat, Robert; Pereyre, Michel; Petraud, Michel
Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 7-8 p. 334 - 344
