in water heating {Co(NH3)4Br2}Br carefully in a small amount of water; formation of Br2; the dark green educt becomes red brown and dissolves fastly with dark colour; fast filtration; ppt. of crude product;;
in neat (no solvent) Kinetics; Irradiation (UV/VIS); photolysis with 265nm at 67-180°C and CF2Br2 pressure 5-200 Torr; mechanism discussed;; quantum yield discussed;;
参考文献
J. Chem. Soc. Faraday Trans. I, , vol. 68, p. 1559 - 1565
