反应条件
in tetrachloromethane; water
byproducts: H3PO4; to suspn. of P2O5 in CCl4 added aq. H2O2 (70 wt percent) dropwise at 2°C under stirring, monitoring of temp., stirred for 2-3 h, added glacial acetic acid (mole ratio 0.5:1:0.3), stirred for 30-45 min.; aq. phase sepd., CCl4 layer extd. (deionized H2O), combined aq. solns.; overall conversion ratio of H2O2 to peroxy acids >95percent;
参考文献
Zhu, Tian; Chang, Hou-Min; Kadla, John F.
Canadian Journal of Chemistry, 2003 , vol. 81, # 2 p. 156 - 160
