hydrogen; Rult;(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthylgt;(OCOCH3)2 in methanol
T=15 - 30°C; P=79040.1 Torr; 70 h; Title compound not separated from byproducts;
hydrogen; triethylamine; lt;RuCl((S)-binap)2gt; in tetrahydrofuran; ethanol
T=50°C; P=2280 Torr; 24 h; Yield given. Title compound not separated from byproducts;
参考文献
Saburi, Masahiko; Takeuchi, Hiroshi; Ogasawara, Masamichi; Tsukahara, Touru; Ishii, Youichi; et al.
Journal of Organometallic Chemistry, 1992 , vol. 428, # 1-2 p. 155 - 167
1: With bis(.eta.(2)-ethylene)(2,4,-pentanedionato)rhodium; (S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl in 1,4-dioxane; water
T=100°C; Arylation; 16 h;
2: With hydrogen; palladium on activated charcoal in ethanol
T=20°C; Catalytic hydrogenation; P=1140.08 Torr; 3 h; Saponification; Further stages.;
Weidler,A.-M.; Bergson,G.
Acta Chemica Scandinavica (1947-1973), 1964 , vol. 18, p. 1483 - 1486
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Lee, Taekyu; Jones, J. Bryan
Journal of the American Chemical Society, 1996 , vol. 118, # 3 p. 502 - 508
