hydrogen sulfide in benzene treatment with H2S about 20 min at ambiente temp.;; washing pptn. with CCl4 and drying in vacuum at 2 torr and 150°C;;
参考文献
Gmelin Handbook: V: MVol.B1, 75, page 205 - 207
Full Text Show Details
Femipari Kutato Intezet
Patent: HU149600 , 1962 ;
C. A., 1963 , vol. 58, p. 2187
hydrogen chloride in n-heptane byproducts: carbon monoxide, dihydrogen; under Ar or N2, exclusion of light, at -78°C, warmed to -40°C; pptn. filtered off at room temp.;
in n-heptane byproducts: 1,3,5-trimethylbenzene, H2; under purified Ar atm.; soln. of V(η6-Me3C6H3)2 in heptane was treated with dry HCl; after 2 hs suspn. filtered; solid dried (vac.) at room temp.; elem. anal.;
参考文献
Calderazzo, Fausto; Englert, Ulli; Pampaloni, Guido; Volpe, Manuel
Journal of Organometallic Chemistry, 2005 , vol. 690, # 14 p. 3321 - 3332
