in not given stepwise heating at 80 - 100°C and 150 - 180°C or 250°C; reaction take place in presence of water, alkali sulfates, NaOH, Na2CO3, CaO or S; stepwise addn. of educts;;
参考文献
Hene, E.
Patent: DE555489 , 1932 ;
C. II, 1932 , p. 1692
in neat (no solvent) byproducts: zirconium sulfide; heating of Zr with S; inflammation;; distillation of excess of S; product mixture of zirconium sulfide, ZrO2 and ZrOS;;
参考文献
Wedekind, E.
Liebigs Annalen der Chemie, 1913 , vol. 395, p. 149 - 194
Full Text Show Details
Gmelin Handbook: Zr: MVol., 129, page 332 - 334
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反应条件
in neat (no solvent) pelletizing of mixt. of Fe(CO)5, S and Ta; transferring to ampoules; evacuating, sealing, heating to 1273 K for 20 ds;
参考文献
Vershinin; Mar'evich; Chumarev; Selivanov
Russian Journal of Inorganic Chemistry, 2007 , vol. 52, # 9 p. 1459 - 1463
