1: With monochlorotrifluoromethane T=-196.15°C; Fluorination; chlorination; addition; electric arc; 2: With hydrogenchloride in methanol T=-196.15°C; acidolysis;
参考文献
Journal of the American Chemical Society, , vol. 119, # 22 p. 5091 - 5094
di-tert-butyl peroxide in tetrachloromethane T=20°C; Irradiationposiible mechanism discussed; relative rates of hydrogen abstraction were determined both by EPR technique (Me3COOCMe3) and by GC (this conditions); stereoelectronic effects in this process was compared for a series of 1,3-dioxanes;
参考文献
Journal of the American Chemical Society, , vol. 103, # 3 p. 615 - 619