1-(3'-甲基[1,1'-联苯]-4-基)乙酮合成路线 （共 7 条）
反应条件
C23H35N4O4Pd(1+)*Br(1-); potassium carbonate in water
T=100°C; Suzuki-Miyaura Coupling; 1 h;
参考文献
Li, Liuyi; Wu, Tao; Wang, Jinyun; Wang, Ruihu
ChemPlusChem, 2014 , vol. 79, # 2 p. 257 - 265
反应条件
palladium diacetate; (-)-2-(dicyclohexylphosphino)-2'-(dimethylamino)-1,1'-binaphthyl; cesium fluoride in 1,4-dioxane
Ambient temperature;
参考文献
Old; Wolfe; Buchwald
Journal of the American Chemical Society, 1998 , vol. 120, # 37 p. 9722 - 9723
反应条件
potassium phosphate; BF4(1-)*C31H33ClN5Ni(1+) in ethylene glycol dimethyl ether
T=120°C; Suzuki-Miyaura coupling; 24 h; Inert atmosphereSealed tube;
参考文献
Kuroda, Jun-Ichi; Inamoto, Kiyofumi; Hiroya, Kou; Doi, Takayuki
European Journal of Organic Chemistry, 2009 , # 14 p. 2251 - 2261
反应条件
potassium acetate; palladium diacetate; N,N-dicyclohexylamine in N,N-dimethyl-formamide
T=35°C; 2 h; Inert atmosphere;
参考文献
Rao, Maddali L.N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Tetrahedron Letters, 2010 , vol. 51, # 47 p. 6101 - 6104
反应条件
C34H38Cl2N4Pd; caesium carbonate in 1,4-dioxane
T=100°C; Suzuki coupling; 25 h;
参考文献
Morgan, Brad P.; Galdamez, Gabriela A.; Gilliard Jr., Robert J.; Smith, Rhett C.
Dalton Transactions, 2009 , # 11 p. 2020 - 2028
反应条件
potassium tetrachloropalladate; cesium fluoride
T=70°C; Suzuki coupling; 3 h; Inert atmosphere;
参考文献
Bej, Ansuman; Srimani, Dipankar; Sarkar, Amitabha
Green Chemistry, 2012 , vol. 14, # 3 p. 661 - 667
反应条件
1: potassium tetrachloropalladate; potassium acetate / 1.5 h / 70 °C / Inert atmosphere
2: potassium tetrachloropalladate; cesium fluoride / 3 h / 70 °C / Inert atmosphere
View Scheme
参考文献
Bej, Ansuman; Srimani, Dipankar; Sarkar, Amitabha
Green Chemistry, 2012 , vol. 14, # 3 p. 661 - 667
