反应条件
in tetrahydrofuran byproducts: N2; High Pressure; CuCl2 and NaN3 ground, placed into a stainless steel reactor, solvent added, sealed, heated to ca. 50°C, ca. 100°C, and 185°C with regulated rates (the total react. time of ca. 3-5 d); cooled to room temp., dried (vac.), NaCl sepd. with MeOH under N2, filtered, dried (vac.); obtained as nanocrystals;
参考文献
Choi, Jonglak; Gillan, Edward G.
Inorganic Chemistry, 2005 , vol. 44, # 21 p. 7385 - 7393
