in neat (no solvent, solid phase) PdCl2 and CoO were mixed, sealed in evacuated silica tube, heated at 700°C for 40 h, cooled; leached with EtOH or water, powdered, pelletized, sintered at 600°C for 2 ds;
参考文献
Solid State Communications, , vol. 121, # 4 p. 203 - 205
in dichloromethane CH2Cl2-soln. of C4(CO)12 in pyrex tube put in steel reactor, heated to 110 °C for 4 h, 210 °C at 25 atm for 1 h, cooled, pH=1.00; washed with water, dried in vac. over two nights;
参考文献
Chemical Physics Letters, , vol. 369, # 1-2 p. 198 - 203
in neat (no solvent) byproducts: N,N-dimethylpropionamide; sample heating in TG and DSC apparatus in N2 flow (ca. 20 ml/min) up to 400°C; TG, DTG, DSC;
in neat (no solvent) byproducts: HCl, C6H12N2; air or Ar atmosphere; heating to 380°C; reaction followed by X-ray diffraction, MAS, IR and Raman spectroscopy; elem. anal.;
参考文献
Journal of thermal analysis, , vol. 49, # 2 p. 635 - 647
→
反应条件
in not given cold saturated NH4Cl-solution;;
参考文献
Bulletin de la Societe Chimique de France, , vol. 3, p. 1388 - 1389
