1: anthracene With sodium in tetrahydrofuran T=20°C; Metallation; 2: N-benzoylethylenimine in tetrahydrofuran T=20°C; Ring cleavage; addition; dimerization; reduction; Further byproducts given;
1: anthracene With sodium in tetrahydrofuran T=20°C; Metallation; 2: N-benzoylethylenimine in tetrahydrofuran T=20°C; Ring cleavage; addition; dimerization; reduction; 24 h; Further byproducts given;
Na anthracenide in tetrahydrofuran T=-10°C; 40 h; var. of reagent, time; Product distributionMechanism;
参考文献
Stamm, Helmut; Assithianakis, Petros; Weiss, Rainer; Bentz, Gunther; Buchholz, Berthold
Journal of the Chemical Society, Chemical Communications, 1984 , # 12 p. 753 - 754
