2-甲基-1,4-戊二烯合成路线 (共 28 条)
反应条件
chromium corundum T=250°C;
参考文献
Nasarow; Mawrow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959 , p. 472,482; engl. Ausg. S. 446, 454
反应条件
DpSc-H T=80°C; Product distribution;
参考文献
Bunel, Emilio; Burger, Barbara J.; Bercaw, John E.
Journal of the American Chemical Society, 1988 , vol. 110, # 3 p. 976 - 978
反应条件
3-chloro-benzenecarboperoxoic acid in 1,2-dichloro-ethane T=20°C; 0.5 h; Title compound not separated from byproducts.;
参考文献
Colladon, Marco; Scarso, Alessandro; Sgarbossa, Paolo; Michelin, Rino A.; Strukul, Giorgio
Journal of the American Chemical Society, 2007 , vol. 129, # 24 p. 7680 - 7689
反应条件
{(C8H14)2RhCl2}2; tri-cyclo-hexyl-phosphine in toluene T=150°C; 4 h;
参考文献
Lee, Dae-Yon; Kim, In-Jung; Jun, Chul-Ho
Angewandte Chemie - International Edition, 2002 , vol. 41, # 16 p. 3031 - 3033
反应条件
sodium tetrahydroborate; Hg(NO3)2 Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Bloodworth, A. J.; Khan, Jamil A.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 2450 - 2457
参考文献
Srinivasan,R.; Carlough,K.H.
Journal of the American Chemical Society, 1967 , vol. 89, p. 4932 - 4936
反应条件
1,3,5-trimethyl-benzene in benzene-d6
The mixt. of reagents was sealed under vac. in a NMR tube, heated for 3.5 h at 140°C;; distilled, recrystd. from benzene-hexane;;
参考文献
Flood, Thomas C.; Statler, John A.
Organometallics, 1984 , vol. 3, p. 1795 - 1803
反应条件
in benzene-d6
Heating in a sealed NMR tube for 31 h at 140°C;; distilled,;
参考文献
Flood, Thomas C.; Statler, John A.
Organometallics, 1984 , vol. 3, p. 1795 - 1803
反应条件
T=350°C; P=129287 Torr;
参考文献
Cywinski,N.F.
Journal of Organic Chemistry, 1965 , vol. 30, p. 361 - 364
反应条件
chromium corundum
T=200°C;
参考文献
Lewina et al.
Zhurnal Obshchei Khimii, 1951 , vol. 21, p. 233,235,236; engl.Ausg.S.251,253,254