顺式-6-壬烯-1-醇乙酸酯合成路线 （共 10 条）
反应条件
in acetic acid T=40°C; 6 h;
参考文献
Garcia Martinez, Antonio; Oliver Ruiz, Manuel
Synthesis, 1983 , # 8 p. 663 - 665
反应条件
1-methyl-1H-imidazole in acetonitrile T=20°C; 24 h;
参考文献
Prat, Irene; Font, David; Company, Anna; Junge, Kathrin; Ribas, Xavi; Beller, Matthias; Costas, Miquel
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 5 p. 947 - 956
反应条件
1: 83 percent / conc. hydrochloric acid / 2 h 2: 46 percent / 3-chloroperbenzoic acid / CH2Cl2 / 12 h / Ambient temperature 3: 1.) diphenylphosphine, butyllithium, 2.) methyl iodide / CH2Cl2 / 12 h / Ambient temperature; 1.) THF, hexane, room temp., 7 h, 2.) 30 min 4: 90 percent / acetic acid / 6 h / 40 °C View Scheme
参考文献
Synthesis, , # 8 p. 663 - 665
反应条件
1: 1.) diphenylphosphine, butyllithium, 2.) methyl iodide / CH2Cl2 / 12 h / Ambient temperature; 1.) THF, hexane, room temp., 7 h, 2.) 30 min 2: 90 percent / acetic acid / 6 h / 40 °C View Scheme
参考文献
Synthesis, , # 8 p. 663 - 665
反应条件
1: 46 percent / 3-chloroperbenzoic acid / CH2Cl2 / 12 h / Ambient temperature 2: 1.) diphenylphosphine, butyllithium, 2.) methyl iodide / CH2Cl2 / 12 h / Ambient temperature; 1.) THF, hexane, room temp., 7 h, 2.) 30 min 3: 90 percent / acetic acid / 6 h / 40 °C View Scheme
参考文献
Synthesis, , # 8 p. 663 - 665
反应条件
2: 83 percent / conc. hydrochloric acid / 2 h 3: 46 percent / 3-chloroperbenzoic acid / CH2Cl2 / 12 h / Ambient temperature 4: 1.) diphenylphosphine, butyllithium, 2.) methyl iodide / CH2Cl2 / 12 h / Ambient temperature; 1.) THF, hexane, room temp., 7 h, 2.) 30 min 5: 90 percent / acetic acid / 6 h / 40 °C View Scheme
参考文献
Synthesis, , # 8 p. 663 - 665
反应条件
1: pyridine 2: 1) Li2CuCl4; 2) Mg / 1) abs. THF, -45 deg C; 2) diethyl ether, -45 deg C, 3 h, then -10 deg C, 2.5 h, 0-2 deg C, 2.5 h, room temp., 12 h. View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 24, # 4 p. 646 - 651
Zhurnal Organicheskoi Khimii, , vol. 24, # 4 p. 719 - 724
反应条件
dilithium tetrachlorocuprate; magnesium 1) abs. THF, -45 deg C; 2) diethyl ether, -45 deg C, 3 h, then -10 deg C, 2.5 h, 0-2 deg C, 2.5 h, room temp., 12 h.; Yield given. Multistep reaction;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 24, # 4 p. 646 - 651
Zhurnal Organicheskoi Khimii, , vol. 24, # 4 p. 719 - 724
反应条件
[rhodium(I)(carbonyl)2(acetylacetonate)]; (Ru2(η5-C5Ph4O)2(H)2(CO)4); carbon monoxide; C70H72O2P2; hydrogen in 1,4-dioxane T=120°C; P=3750.38 Torr; 36 h; Inert atmosphereAutoclave;
参考文献
Yuki, Yamato; Takahashi, Kohei; Tanaka, Yoshiyuki; Nozaki, Kyoko
Journal of the American Chemical Society, 2013 , vol. 135, # 46 p. 17393 - 17400
反应条件
[rhodium(I)(carbonyl)2(acetylacetonate)]; (Ru2(η5-C5Ph4O)2(H)2(CO)4); carbon monoxide; C70H72O2P2; hydrogen in 1,4-dioxane T=120°C; P=3750.38 Torr; 36 h; Inert atmosphereAutoclave;
参考文献
Journal of the American Chemical Society, , vol. 135, # 46 p. 17393 - 17400
