6,10,14-三甲基十五碳-5,9,13-三烯-2-酮合成路线 （共 13 条）
反应条件
ammonium chloride T=160°C; 16 h; Autoclave; Product distribution / selectivity;
参考文献
DSM IP ASSETS B.V.; BONRATH, Werner; KUENZI, Rolf; AQUINO, Fabrice
Patent: WO2010/46199 A2, 2010 ;
Location in patent: Page/Page column 7 ;
反应条件
ethanol; Petroleum ether beim Spalten des nicht naeher beschriebenen Farnesylacetessigesters mit methylalkoh. KOH;
参考文献
Helvetica Chimica Acta, , vol. 27, p. 1299
Helvetica Chimica Acta, , vol. 22, p. 395
反应条件
1: pyridine; phosphorus tribromoide / -15 °C 2: ethanol; petroleum ether / beim Spalten des nicht naeher beschriebenen Farnesylacetessigesters mit methylalkoh. KOH View Scheme
参考文献
Helvetica Chimica Acta, , vol. 22, p. 395
反应条件
aluminum isopropoxide
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 25, p. 1914 - 1921
反应条件
(i) PBr3, Et2O, (ii) /BRN= 4160456/, MeOH, (iii) KOH; Multistep reaction;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 25, p. 1914 - 1921
反应条件
(i) Et2O, (ii) KHSO4; Multistep reaction;
参考文献
Doklady Chemistry, , vol. 132, # 4 p. 607 - 608
Doklady Akademii Nauk SSSR, , vol. 132, # 4 p. 829 - 831
反应条件
hydrogen; platinum(IV) oxide in methanol
参考文献
Doklady Chemistry, , vol. 132, # 4 p. 607 - 608
Doklady Akademii Nauk SSSR, , vol. 132, # 4 p. 829 - 831
反应条件
1: potassium tert-pentylate; diethyl ether / -15 °C 2: ethanol; platinum / partielle Hydrierung View Scheme
参考文献
Helvetica Chimica Acta, , vol. 27, p. 1299
反应条件
1: (i) KOH, (ii) /BRN= 906677/ 2: H2, quinoline / Lindlar catalyst / cyclohexane 3: Al(OiPr)3 4: (i) KOH, (ii) /BRN= 906677/ 5: H2, quinoline / Lindlar catalyst / cyclohexane 6: AlCl3 / diethyl ether View Scheme
参考文献
Weichet,J. et al.
Collection of Czechoslovak Chemical Communications, 1960 , vol. 25, p. 1914 - 1921
反应条件
1: potassium tert-butylate; diethyl ether / -20 °C
2: ethanol; palladium-calcium carbonate / partielle Hydrierung
3: pyridine; PBr3 / -15 °C
4: potassium acetate; acetone / folgendes Verseifen mit siedender methylalkoh.KOH
View Scheme
参考文献
Ruzicka; Firmenich
Helvetica Chimica Acta, 1939 , vol. 22, p. 395
