甲基 3,4,6-O-三乙酰基-2-脱氧-2-邻苯二甲酰亚氨基-beta-D-吡喃葡萄糖苷合成路线 (共 20 条)
反应条件
tin(IV) chloride in dichloromethane
参考文献
Sabesan, Subramaniam
Patent: US2006/286149 A1, 2006 ;
Location in patent: Page/Page column 11 ;
反应条件
boron trifluoride diethyl etherate in dichloromethane T=-30°C; 1 h;
参考文献
Grundler, Gerhard; Schmidt, Richard R.
Carbohydrate Research, 1984 , vol. 135, p. 203 - 218
反应条件
N-iodo-succinimide; trifluorormethanesulfonic acid in diethyl ether; 1,2-dichloro-ethane T=20°C; 0.0833333 h;
参考文献
Zuurmond, H. M.; Klein, P. A. M. van der; Wildt, J. de; Marel, G. A. van der; Boom, J. H. van
Journal of Carbohydrate Chemistry, 1994 , vol. 13, # 2 p. 323 - 340
反应条件
calcium sulfate; mercury(II) cyanide in benzene 24 h; Ambient temperature;
参考文献
Bundle, David R.; Josephson, Staffan
Canadian Journal of Chemistry, 1980 , vol. 58, p. 2679 - 2685
反应条件
silver zeolite in dichloromethane 1 h; Ambient temperature;
参考文献
Schwartz; Lee; Carver; Krepinsky
Canadian Journal of Chemistry, 1985 , vol. 63, # 5 p. 1073 - 1079
反应条件
3 A molecular sieve in acetonitrile electrochemical synthesis: one compartment, three-electrode, air-tight cell, vitrous carbon anode and Pt catode, 0.2 M LiBF4 as supporting electrolyte, constant potential 1.52 V (vs standard calomel reference electrode);
参考文献
Balovoine, Gilbert; Berteina, Sabine; Gref, Aurore; Fischer, Jean-Claude; Lubineau, Andre
Journal of Carbohydrate Chemistry, 1995 , vol. 14, # 8 p. 1217 - 1236
反应条件
1: 35 percent / benzylamine / 0.05 h / 0 °C 2: 73 percent / NaH / CH2Cl2 / 0.17 h 3: 65 percent / 0.1M diethylether*borontrifluoride / CH2Cl2 / 1 h / -30 °C View Scheme
参考文献
Carbohydrate Research, , vol. 135, p. 203 - 218
反应条件
1: 73 percent / NaH / CH2Cl2 / 0.17 h 2: 65 percent / 0.1M diethylether*borontrifluoride / CH2Cl2 / 1 h / -30 °C View Scheme
参考文献
Carbohydrate Research, , vol. 135, p. 203 - 218
反应条件
1: pyridine 2: hydrogen chloride / Behandeln des Reaktionsprodukts mit Acetanhydrid und Pyridin View Scheme
参考文献
Yakugaku Zasshi, , vol. 77, p. 726,730
Chem.Abstr., , p. 17763
反应条件
1.1: sodium hydroxide / methanol; water / 0.25 h 1.2: 20 °C 2.1: pyridine; 4-(N,N-dimethlyamino)pyridine / 48 h / 20 °C / |Inert atmosphere; |Large scale 3.1: tin(IV) chloride / dichloromethane View Scheme