1,1,1,2,4,4,4-七氟-2-丁烯合成路线 （共 5 条）
反应条件
hydrogen; Ni/Cu/Cr/CaF2
T=350 - 401°C; 0.00405556 - 0.00541667 h; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: US2009/156869 A1, 2009 ;
Location in patent: Page/Page column 5 ;
反应条件
hydrogen; Ni/Cu/Cr/CaF2
T=383 - 401°C; 0.00441667 - 0.00444444 h; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: US2009/156869 A1, 2009 ;
Location in patent: Page/Page column 5 ;
反应条件
tetramethylene sulfide; potassium fluoride
T=190°C;
参考文献
Chambers, Richard D.; Mullins, Steven J.; Roche, Alex J.; Vaughan, Julian F. S.
Journal of the Chemical Society, Chemical Communications, 1995 , # 8 p. 841 - 842
反应条件
tetramethylene sulfide; potassium fluoride; sulfuric acid
1) 190 deg C; Multistep reaction. Yields of byproduct given;
参考文献
Chambers, Richard D.; Mullins, Steven J.; Roche, Alex J.; Vaughan, Julian F. S.
Journal of the Chemical Society, Chemical Communications, 1995 , # 8 p. 841 - 842
反应条件
hydrogen; 5 Pd(II)/C(eggshell) in ethanol
T=90°C; P=26618.1 Torr; Cooling with dry ice;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: US2010/174123 A1, 2010 ;
Location in patent: Page/Page column 5 ;
