potassium hydroxide

D-glucose in methanol T=29 - 30°C; 120 h; Bacillus spec.;

manganese(IV) oxide; chloroform

1.1: potassium carbonate / chloroform / 6 h / Reflux 2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 2.75 h / -78 °C 2.2: -78 - 20 °C 3.1: potassium tert-butylate / tetrahydrofuran; 1-methyl-pyrrolidin-2-one / 0 - 20 °C 3.2: 2.25 h / 0 - 20 °C 4.1: lithium aluminium tetrahydride / tetrahydrofuran / 1.25 h / 0 - 20 °C / Inert atmosphere 5.1: Reflux 6.1: palladium 10 on activated carbon; hydrogen / methanol / 3102.97 Torr 7.1: magnesium / diethyl ether / Inert atmosphere; Reflux 7.2: 20 °C 8.1: potassium carbonate; thiophenol / 1-methyl-pyrrolidin-2-one / 0.5 h / 220 - 230 °C / Inert atmosphere View Scheme

1: 3-chloro-benzenecarboperoxoic acid / chloroform; isopropyl alcohol / 0.42 h / -5 °C 2: FeCl3·6H2O; iron / chloroform; isopropyl alcohol / 36 h / 20 °C View Scheme

1: triethylamine / dichloromethane / 1 h / 0 °C 2: lithium aluminium tetrahydride / tetrahydrofuran / 1.75 h / 0 - 20 °C 3: platinum(IV) oxide; hydrogen / methanol / 1 h / 3000.3 Torr 4: boron tribromide / dichloromethane / 0.5 h / 23 - 26 °C View Scheme

β-nicotinamide dinucleotide phosphate sodium salt; NADP+-dependent morphine dehydrogenase; 1-(3-hydroxypropyl)-3-methylimidazolium glycolate; water in phosphate buffer T=30°C; 24 h; Title compound not separated from byproducts.;

暂无反应条件数据

boron tribromide in dichloromethane; chloroform T=25°C; 0.25 h;

Wistar rat hepatocytes T=37°C; Elimination; 2 h; Kinetics; Further Variations:Reagents;