1-苄基-7-氧杂双环[4.1.0]庚烷合成路线 （共 9 条）
反应条件
methanol; toluene-4-sulfonic acid in dichloromethane T=25°C; 12 h;
参考文献
Journal of Organic Chemistry, , vol. 47, # 15 p. 2917 - 2923
反应条件
toluene-4-sulfonic acid in dichloromethane T=25°C; 12 h; different reaction times, solv., and temp., other reagents; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 47, # 15 p. 2917 - 2923
参考文献
Tiffeneau; Porcher
Bulletin de la Societe Chimique de France, 1922 , vol. <4> 31, p. 328
反应条件
1: p-TsOH*H2O / 1 h / 160 °C
2: 1.) p-TsOH*H2O, 2.) m-CPBA, NaHCO3 / 1.) 160 deg C, 1 h, 2.) hexane, room temperature, 1.5 h
View Scheme
参考文献
Nakamura, Yutaka; Takeuchi, Seiji; Ohgo, Yoshiaki; Yamaoka, Makoto; Yoshida, Akihiro; Mikami, Koichi
Tetrahedron, 1999 , vol. 55, # 15 p. 4595 - 4620
反应条件
sodium hydroxide; water; N-bromoacetamide
1.) dioxane, heating, 5 min; Yield given. Multistep reaction;
参考文献
Costantino, Paolo; Crotti, Paolo; Ferretti, Maria; Macchia, Franco
Journal of Organic Chemistry, 1982 , vol. 47, # 15 p. 2917 - 2923
反应条件
1: diethyl ether / Ambient temperature
2: p-TsOH*H2O / 1 h / 160 °C
3: 1.) p-TsOH*H2O, 2.) m-CPBA, NaHCO3 / 1.) 160 deg C, 1 h, 2.) hexane, room temperature, 1.5 h
View Scheme
参考文献
Nakamura, Yutaka; Takeuchi, Seiji; Ohgo, Yoshiaki; Yamaoka, Makoto; Yoshida, Akihiro; Mikami, Koichi
Tetrahedron, 1999 , vol. 55, # 15 p. 4595 - 4620
反应条件
1: diethyl ether / Ambient temperature
2: p-TsOH*H2O / 1 h / 160 °C
3: 1.) p-TsOH*H2O, 2.) m-CPBA, NaHCO3 / 1.) 160 deg C, 1 h, 2.) hexane, room temperature, 1.5 h
View Scheme
参考文献
Nakamura, Yutaka; Takeuchi, Seiji; Ohgo, Yoshiaki; Yamaoka, Makoto; Yoshida, Akihiro; Mikami, Koichi
Tetrahedron, 1999 , vol. 55, # 15 p. 4595 - 4620
反应条件
diethyl ether; silver nitrate
参考文献
Tiffeneau; Porcher
Bulletin de la Societe Chimique de France, 1922 , vol. <4> 31, p. 328
参考文献
Mousseron et al.
Bulletin de la Societe Chimique de France, 1946 , p. 629,632
