1,1,1,3,4,4,4-七氟-3-(三氟甲基)-2-丁酮合成路线 (共 4 条)
反应条件
potassium fluoride; trifluoroacetic anhydride in diethylene glycol dimethyl ether
参考文献
3M Innovative Properties Company
Patent: US2003/89877 A1, 2003 ;
反应条件
potassium fluoride in diethylene glycol dimethyl ether
T=100 - 110°C; 8 h; Autoclave;
参考文献
Wlassics, Ivan; Tortelli, Vito; Carella, Serena; Monzani, Cristiano; Marchionni, Giuseppe
Molecules, 2011 , vol. 16, # 8 p. 6512 - 6540
反应条件
cesium fluoride
1 h; Heating;
参考文献
Kurykin, M. A.; German, L. S.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, # 11 p. 2389
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 11 p. 2649
反应条件
oxygen
photochemical oxidation, short reaction time; Product distribution;
参考文献
Haszeldine, R. N.
Journal of Fluorine Chemistry, 1985 , vol. 29, p. 4