甲基 3-O-苄基-ALPHA-L-吡喃鼠李糖苷合成路线 （共 7 条）
反应条件
diphenylboronic ethanolamine complex; silver(l) oxide in acetonitrile
T=40°C; 48 h; Inert atmosphere; regioselective reaction;
参考文献
Chan, Lina; Taylor, Mark S.
Organic Letters, 2011 , vol. 13, # 12 p. 3090 - 3093
反应条件
lithium aluminium tetrahydride; aluminium trichloride in diethyl ether; dichloromethane
参考文献
Liptak,A.; Nanasi,P.; Neszmelyi,A.; Wagner,H.
Tetrahedron, 1980 , vol. 36, p. 1261
反应条件
1: toluene-p-sulphonic acid / dimethylformamide / 2 h / 70 - 75 °C
2: 94.4 percent / 1N NaOMe / methanol / 16 h / Ambient temperature
3: 88 percent / LAH, AlCl3 / CH2Cl2; diethyl ether
View Scheme
参考文献
Liptak,A.; Nanasi,P.; Neszmelyi,A.; Wagner,H.
Tetrahedron, 1980 , vol. 36, p. 1261
反应条件
1: 94.4 percent / 1N NaOMe / methanol / 16 h / Ambient temperature
2: 88 percent / LAH, AlCl3 / CH2Cl2; diethyl ether
View Scheme
参考文献
Liptak,A.; Nanasi,P.; Neszmelyi,A.; Wagner,H.
Tetrahedron, 1980 , vol. 36, p. 1261
反应条件
1: toluene-p-sulphonic acid / dimethylformamide / 2 h / 70 - 75 °C
2: 94.4 percent / 1N NaOMe / methanol / 16 h / Ambient temperature
3: 88 percent / LAH, AlCl3 / CH2Cl2; diethyl ether
View Scheme
参考文献
Liptak,A.; Nanasi,P.; Neszmelyi,A.; Wagner,H.
Tetrahedron, 1980 , vol. 36, p. 1261
反应条件
di(n-butyl)tin oxide
1. toluene, 2 h, reflux; 2. DMF, r.t., 18 h; Yield given. Multistep reaction;
参考文献
Kovac; Edgard
Journal of Organic Chemistry, 1992 , vol. 57, # 8 p. 2455 - 2467
反应条件
triethylamine; tin(ll) chloride in ethyl acetate
T=110°C; 32 h; various reagent concentration, solvent; Product distribution;
参考文献
Toman, Rudolf; Rosik, Jozef; Zikmund, Miroslav
Carbohydrate Research, 1982 , vol. 103, p. 165 - 169
