2-乙酰基-3,4-二氢-5,8-二甲氧基萘合成路线 （共 27 条）
反应条件
1: 98 percent / potassium t-butoxide / dimethylsulfoxide / 6 h / Ambient temperature
2: 10 percent / POCl3 / CHCl3 / 4 h / Heating
View Scheme
参考文献
Rao, A. V. Rama; Deshpande, V. H.; Sathaye, K. M.; Jaweed, S. M.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 697 - 702
反应条件
1: 90 percent / potassium carbonate / acetone / 48 h / Heating
2: 98 percent / potassium t-butoxide / dimethylsulfoxide / 6 h / Ambient temperature
3: 10 percent / POCl3 / CHCl3 / 4 h / Heating
View Scheme
参考文献
Rao, A. V. Rama; Deshpande, V. H.; Sathaye, K. M.; Jaweed, S. M.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 697 - 702
反应条件
1: 40 percent / potassium metal, NH3 (liquid) / 1) -33 deg C, 30 min, 2) r.t., 3 h
2: 98 percent / potassium t-butoxide / dimethylsulfoxide / 6 h / Ambient temperature
3: 10 percent / POCl3 / CHCl3 / 4 h / Heating
View Scheme
参考文献
Rao, A. V. Rama; Deshpande, V. H.; Sathaye, K. M.; Jaweed, S. M.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 697 - 702
反应条件
2: 48 percent / pyridinium dichromate
View Scheme
参考文献
Reddy, M. Parameswara; Rao, G. S. Krishna
Tetrahedron Letters, 1981 , vol. 22, # 36 p. 3549 - 3550
反应条件
sulfuric acid
0.166667 h; Ambient temperature;
参考文献
Giardino, Pietro; Vigevani, Aristide; Bernardi, Luigi; Arcamone, Federico
Gazzetta Chimica Italiana, 1980 , vol. 110, # 2/3 p. 101 - 104
反应条件
4-(N,N-dimethlyamino)pyridine; methanesulfonyl chloride; triethylamine
Elimination;
参考文献
Chavan, Subhash P.; Subbarao, Y. Tripura; Gopal, Chittiboyina Amar
Journal of Chemical Research - Part S, 1999 , # 6 p. 380 - 381
反应条件
1: 90 percent / hydrogen / 5percent Pd/C / ethanol / 5 h / 1034.3 Torr / Ambient temperature
2: 1) potassium t-butoxide, O2, 2) gl. acetic acid, zinc dust / 1) t-butanol, 35 deg C, 5 min, 2) 6 h, r.t.
3: 70 percent / aluminium chloride, sodium chloride / 0.08 h / 180 °C
View Scheme
参考文献
Tanno; Terashima
Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 3 p. 811 - 820
