(3-甲氧基-4-硝基-苯基)-苯基-甲酮合成路线 （共 6 条）
反应条件
oxygen; pivalaldehyde; [1,2-C6H4(NCOCONMe)2-Co(III)](1-)*NMe4(1+) in acetonitrile
参考文献
Barroso, Santiago; Blay, Gonzalo; Cardona, Luz; Fernandez, Isabel; Garcia, Begona; Pedro, Jose R.
Journal of Organic Chemistry, 2004 , vol. 69, # 20 p. 6821 - 6829
反应条件
1.1: LDA; HMPA / heptane; tetrahydrofuran; ethylbenzene / 0.5 h / -78 °C
1.2: 75 percent / HMPA / heptane; tetrahydrofuran; ethylbenzene / 0.17 h / -78 °C
2.1: 93 percent / KOH / ethanol / 20 °C
3.1: 80 percent / O2; pivalaldehyde; substituted o-phenylenediamine Co(III) complex / acetonitrile
View Scheme
参考文献
Barroso, Santiago; Blay, Gonzalo; Cardona, Luz; Fernandez, Isabel; Garcia, Begona; Pedro, Jose R.
Journal of Organic Chemistry, 2004 , vol. 69, # 20 p. 6821 - 6829
反应条件
1.1: LDA; HMPA / heptane; tetrahydrofuran; ethylbenzene / 0.5 h / -78 °C
1.2: 75 percent / HMPA / heptane; tetrahydrofuran; ethylbenzene / 0.17 h / -78 °C
2.1: 93 percent / KOH / ethanol / 20 °C
3.1: 80 percent / O2; pivalaldehyde; substituted o-phenylenediamine Co(III) complex / acetonitrile
View Scheme
参考文献
Barroso, Santiago; Blay, Gonzalo; Cardona, Luz; Fernandez, Isabel; Garcia, Begona; Pedro, Jose R.
Journal of Organic Chemistry, 2004 , vol. 69, # 20 p. 6821 - 6829
反应条件
1: 93 percent / KOH / ethanol / 20 °C
2: 80 percent / O2; pivalaldehyde; substituted o-phenylenediamine Co(III) complex / acetonitrile
View Scheme
参考文献
Barroso, Santiago; Blay, Gonzalo; Cardona, Luz; Fernandez, Isabel; Garcia, Begona; Pedro, Jose R.
Journal of Organic Chemistry, 2004 , vol. 69, # 20 p. 6821 - 6829
反应条件
1.1: n-BuLi / tetrahydrofuran; hexane / 0.25 h
1.2: DDQ / tetrahydrofuran; hexane
2.1: H2SO4 / H2O; dioxane
View Scheme
参考文献
Katritzky, Alan R.; Chassaing, Christophe; Toader, Dorin; Gill, Katherine
Journal of Chemical Research - Part S, 1999 , # 8 p. 504 - 505
反应条件
1.1: n-BuLi / tetrahydrofuran; hexane / 0.25 h
1.2: DDQ / tetrahydrofuran; hexane
2.1: H2SO4 / H2O; dioxane
View Scheme
参考文献
Katritzky, Alan R.; Chassaing, Christophe; Toader, Dorin; Gill, Katherine
Journal of Chemical Research - Part S, 1999 , # 8 p. 504 - 505
