H2 in perdeuterocyclohexane byproducts: CF2H2; under N2; in a resealable NMR tube Zr complex was dissolved in cyclohexane-d12, the tube was freeze-pump-thaw degassed 3 times, CHF2Cl was condensed at -196°C , H2 was added, upon thawing, a yellow ppt. formed; not isolated, monitored by NMR;
参考文献
Journal of the American Chemical Society, , vol. 123, # 44 p. 10973 - 10979
H2 in perdeuterocyclohexane byproducts: methane; under N2; in a NMR tube Zr complex was dissolved in cyclohexane-d12, thetube was freeze-pump-thaw degassed 3 times, CHF2Cl was condensed at -19 6°C , H2 was added, upon thawing, a yellow ppt. formed, the mixt.was heated at 120°C for 10 d; not isolated, monitored by NMR;
参考文献
Journal of the American Chemical Society, , vol. 123, # 44 p. 10973 - 10979
Diaz, L.; Santos, M.; Sigueenza, C. L.; Simeonov, S. A.; Gonzalez-Diaz, P. F.; et al.
Journal of the Chemical Society, Faraday Transactions, 1993 , vol. 89, # 21 p. 3907 - 3912