2-甲基-4,6-二硝基苯胺合成路线 （共 57 条）
反应条件
1: Kochen der Diazoniumverbindung mit Alkohol.Diazotization 2: chromic acid mixture View Scheme
参考文献
Staedel
Justus Liebigs Annalen der Chemie, 1883 , vol. 217, p. 172
反应条件
1: Kochen der Diazoniumverbindung mit Alkohol.Diazotization 2: alcoholic ammonium sulfide View Scheme
参考文献
Staedel
Justus Liebigs Annalen der Chemie, 1883 , vol. 217, p. 172
反应条件
1: nitric acid; N2O3 / 0 °C / Behandeln des Diazoniumnitrats mit NaNO2 und Erwaermen des Reaktionsprodukts mit Salpetersaeure 2: Cr2O3-H2SO4 / 50 °C 3: water View Scheme
参考文献
Koerner; Contardi
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1915 , vol. <5> 24 I, p. 891
反应条件
Diazotization.Behandlung des Diazoniumnitrats mit Alkohol;
参考文献
Staedel
Justus Liebigs Annalen der Chemie, 1883 , vol. 217, p. 172
反应条件
1: H2 / Raney nickel / ethanol / 1.5 h / Ambient temperature 2: 30 percent / H2O / 0.17 h / Heating 3: 70 percent / acetic anhydride / 1 h / Ambient temperature 4: 70 percent / LiAlH4 / tetrahydrofuran / 4 h / 0 - 5 °C 5: 65 percent / conc. H2SO4, KNO3 / acetic acid / 1.) 0 deg C, 2.) 20 deg C, 90 min 6: 1.) H2 / 1.) Raney nickel / 1.) ethanol, room temperature, 60 min, 2.) room temperature View Scheme
参考文献
Nyhammar, Tomas; Grivas, Spiros
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1986 , vol. 40, # 7 p. 583 - 587
反应条件
1: H2 / Raney nickel / ethanol / 1.5 h / Ambient temperature 2: 30 percent / H2O / 0.17 h / Heating 3: 70 percent / acetic anhydride / 1 h / Ambient temperature 4: 70 percent / LiAlH4 / tetrahydrofuran / 4 h / 0 - 5 °C View Scheme
参考文献
Nyhammar, Tomas; Grivas, Spiros
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1986 , vol. 40, # 7 p. 583 - 587
反应条件
1: H2 / Raney nickel / ethanol / 1.5 h / Ambient temperature 2: H2O / 0.17 h / Heating View Scheme
参考文献
Nyhammar, Tomas; Grivas, Spiros
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1986 , vol. 40, # 7 p. 583 - 587
反应条件
1: H2 / Raney nickel / ethanol / 1.5 h / Ambient temperature 2: 30 percent / H2O / 0.17 h / Heating View Scheme
参考文献
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, , vol. 40, # 7 p. 583 - 587
反应条件
ethanol; ammonia
T=120 - 130°C;
参考文献
Staedel
Justus Liebigs Annalen der Chemie, 1883 , vol. 217, p. 172
反应条件
ammonia
T=175 - 185°C;
参考文献
Barr
Chemische Berichte, 1888 , vol. 21, p. 1243
