Howarth, Jonathan N.; Pletcher, Derek
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1987 , vol. 83, # 9 p. 2787 - 2794
sodium in neat (no solvent) passing excess AlCl3 vapor over Na in a iron tube at 200-300°C;completion of the reaction by heating the mixture of Al and NaAlCl3 in pots of clay or cast iron until beginning vaporization of NaAlCl3;; removal and melting of Al balls;;
in toluene under purified Ar atm.; AlCl3 added to soln. of Ti(η6-MeC6H5)2 in toluene; mixt. stirred for 18 h at room temp.; solid sepd. by filtration; washed (toluene); dried (vac.); identified asAl; soln. evapd. to dryness; solid washed (heptane); dried (vac.); iden tified as Ti-Al complex;
参考文献
Journal of Organometallic Chemistry, , vol. 690, # 14 p. 3321 - 3332
in neat (no solvent, solid phase) byproducts: LiCl; Electrochem. Process; solid state react.; inside ball-mill at room temp., ball-to-powder ratio35:1 for 180 min; LiCl washed with nitromethane, traces of Al(OH)3 by XRD;
参考文献
Paskevicius; Webb; Pitt; Blach; Hauback; Gray; Buckley
Journal of Alloys and Compounds, 2009 , vol. 481, # 1-2 p. 595 - 599
