1: With 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid in dichloromethane
Baeyer-Villiger reaction; 72 h;
2: With sodium methylate in methanol
0.25 h; Heating; Further stages.;
aluminium trichloride
T=130°C; Fries rearrangement; 0.25 h; Further byproducts.;
参考文献
Oliveira, Ana M. A. G.; Oliveira-Campos, Ana M. F.; Raposo, M. Manuela M.; Griffiths, John; Machado, Antonio E. H.
Tetrahedron, 2004 , vol. 60, # 29 p. 6145 - 6154
1: 94 percent / pyridine / 3 h / Heating
2: 28 percent Chromat. / AlCl3 / 0.25 h / 130 °C
View Scheme
参考文献
Oliveira, Ana M. A. G.; Oliveira-Campos, Ana M. F.; Raposo, M. Manuela M.; Griffiths, John; Machado, Antonio E. H.
Tetrahedron, 2004 , vol. 60, # 29 p. 6145 - 6154
