in deuterated toluene byproducts: H2; soln. of monochlorogallane in toluene-d8 left at room temp. for period of days; monitored by (1)H and (71)Ga NMR spectra;
in tetrahydrofuran byproducts: KBr; soln. of 2 molar equiv. of Fe complex in THF added dropwise to a soln. of Ga dimer at room temp. under N2 and vigorous stirring; stirred for an additional 8 h; colour of the mixt. turned to yellowish brown, gray ppt.formed; filtered, evapd., redissolved in Et2O, cooled to -4°C; crystals sepd. off; identified by elem. anal. and single crystal X-ray diffraction;
参考文献
Linti, Gerald; Li, Guangming; Pritzkow, Heinz
Journal of Organometallic Chemistry, 2001 , vol. 626, # 1-2 p. 82 - 91
in tetrahydrofuran byproducts: KCl; soln. of 4 molar equiv. of Fe complex in THF added dropwise to a soln. of Ga dimer at -78°C under N2 with stirring; warmed to room temp. and stirred for an additional 8 h; colour of the mixt. turned to yellowish brown, gray ppt. formed; filtered, evapd., redissolved in Et2O, cooled to -4°C; crystals sepd. off; identified by elem. anal. and single crystal X-ray diffraction;
参考文献
Linti, Gerald; Li, Guangming; Pritzkow, Heinz
Journal of Organometallic Chemistry, 2001 , vol. 626, # 1-2 p. 82 - 91
