hydrogen; chlorine in gas byproducts: WC(1-x), HCl; react. in a hydrogen-chlorine CVD reactor, react. from 300 to 1700 K, product ratio depending on the molar ratio of H2, Cl2, WCl6 and CH4; determination by powder energy-dispersive X-ray analysis;
参考文献
Journal of the Less-Common Metals, , vol. 163, p. 269 - 280
in further solvent(s) Electrolysis; in furfural soln.;
参考文献
McKee, J. R.; Mann, Ch. A.; Montillon, G. H.
Trans. Am. Electrochem. Soc., 1928 , vol. 53, p. 333
Full Text Show Details
Gmelin Handbook: W: MVol., 1.1.3, page 25 - 31
Russian Journal of Inorganic Chemistry, , vol. 42, # 4 p. 469 - 475
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反应条件
in water High Pressure; 3 equiv. of Br-compd. was added to W-compd. soln. under stirring, ppt. was filtered off, dried at room temp., further Br-compd. was added, Swagelok cell, heating at 1000 °C for 10 h; gradual cooling to room temp.;
参考文献
Journal of Physical Chemistry B, , vol. 109, # 41 p. 19056 - 19059
in melt Electrolysis; in carbon or nickel melting pot like cathode;
参考文献
W: MVol., 1.1.3, page 25 - 31
AU1821176 , ;
→
反应条件
in water High Pressure; 3 equiv. of Br-compd. was added to W-compd. soln. under stirring, ppt. was filtered off, dried at room temp., further Br-compd. was added, Swagelok cell, heating at 900 °C for 10 h; gradual cooling to room temp.;
参考文献
Journal of Physical Chemistry B, , vol. 109, # 41 p. 19056 - 19059
