ClF3 admitting into reaction vessel (Pyrex glass) with silicon (initial p(ClF3)=54300 Pa, reaction duration 1-2 min); gravimetric and volumetric monitoring after 10 min at room temp.;
参考文献
Garabin, V. F.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1979 , vol. 24, p. 1606 - 1608
Zhurnal Neorganicheskoi Khimii, 1979 , vol. 24, p. 2892 - 2896
ClF3 admitting into reaction vessel (Pyrex glass) with silicon (initial p(ClF3)=38300 Pa, reaction duration 1-2 min); gravimetric and volumetric monitoring after 10 min at room temp.;
参考文献
Garabin, V. F.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1979 , vol. 24, p. 1606 - 1608
Zhurnal Neorganicheskoi Khimii, 1979 , vol. 24, p. 2892 - 2896
1,1-dibromomethane in gaseous matrix
Kinetics; Irradiation (UV/VIS); gaseous argon containing CH2Br2 and SiH4 was passed through a reactor, Cl atoms were produced by pulsed photodissociation of CH2Br2 by means of radiation from a flash lamp (temp. 295 to 575 K, pressure 3.33 to 40.1 kPa);; not isolated, monitored by time-resolved atomic resonance fluorescence spectroscopy;;
参考文献
Ding, Luying; Marshall, Paul
Journal of Physical Chemistry, 1992 , vol. 96, # 5 p. 2197 - 2201
