in gaseous matrix
Irradiation (UV/VIS); Irradn. (220-1000 nm, 30 min) of Ar matrix contg. starting materials.; Photochem. react. is followed by IR spectroscopy.;
参考文献
Withnall,R.; Andrews,L.
Journal of the American Chemical Society, 1985 , vol. 107, p. 2567
methyl bromide; copper in neat (no solvent)
Si-Cu (8:2) and CH3Br at 275°C;;
参考文献
Rochow, E. G.
Journal of the American Chemical Society, 1945 , vol. 67, p. 963 - 965
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Gmelin Handbook: Si: MVol.C, 60, page 170 - 173
in neat (no solvent)
reaction of a mixture of Cl2 and O2 (2:1) with Si in a glass tube at red heat; further products;; condensation and fractionation;;
