反应条件
in hexane byproducts: hydrogen, carbon monoxide; under N2, reaction in a thick-walled Pyrex ampoule, 7d at 30°C; evapn., volatile material contained no unchanged SiH4, while Fe(CO)5 (20 - 30percent of iron) was found in the hexane fraction. Chromy. of the residue on silica plates (hexane as eluant) gave orange Si(Fe2(CO)8)2, red needle-shaped crystals from CH2Cl2/hexane;
参考文献
Journal of Organometallic Chemistry, , vol. 350, p. 207 - 216
