in nitric acid
Fe is dissolved in HNO3 (d = 1.034), formation of Fe(NO3)2 and NH3;;
参考文献
Scheurer-Kestner, A.
Ann. Chim. Phys., 1859 , vol. 55, p. 330 - 330
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Scheurer-Kestner, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1858 , vol. 47, p. 927 - 927
Sabatier, P.; Senderens, J.-B.
Ann. Chim. Phys., 1896 , vol. 7, p. 388
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Sabatier, P.; Senderens, J.-B.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1895 , vol. 120, p. 1212
in nitric acid
Fe is dissolved in dild HNO3 without any evolution of gas, formation of NO in form of dark clouds in the Fe(NO3)2 soln., partially reduction to NH3;;
参考文献
Heldt, W.
Journal fuer Praktische Chemie (Leipzig), 1863 , vol. 90, p. 266 - 266
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Ordway, J. M.
Am. J. Sci., 1865 , vol. 40, p. 330 - 330
in nitric acid
Fe is dissolved in HNO3 (34percent, d =1.21), at the beginning Fe is dissolved quickly with evolution of gas, then slowly without evolution of gas and formation of Fe(NO3)3 and traces of NO2 and NH3;;
参考文献
Gautier, H.; Charpy, G.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 112, p. 1451 - 1451
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反应条件
in water
reaction of NH4NO3 with Fe to Fe(NO3)2, NH3 and N2;;