(2,2-二溴乙烯基)苯合成路线 （共 99 条）
反应条件
Pd2(dppf) in tetrahydrofuran T=65°C; Negishi coupling; Product distribution; Further Variations:Reagents;
参考文献
Andrei, Daniela; Wnuk, Stanislaw F.
Journal of Organic Chemistry, 2006 , vol. 71, # 1 p. 405 - 408
反应条件
1: With oxygen T=70°C; 180 h; 2: With water T=20°C; 12 h; Further stages.;
参考文献
Bayatyan; Saakyan
Russian Journal of Applied Chemistry, 2006 , vol. 79, # 11 p. 1849 - 1852
反应条件
potassium fluoride in N,N-dimethyl-formamide T=130°C; 12 h; Inert atmosphere; Reagent/catalystConcentrationSolventTemperatureTime; regioselective reaction;
参考文献
Liu, Guoping; Cong, Xuefeng; He, Jiaheng; Luo, Shunzhong; Wu, Di; Lan, Jingbo
Journal of Chemical Research, 2012 , vol. 36, # 12 p. 687 - 690
反应条件
PEG-400; sodium hydroxide; bis[1,2-bis(diphenylphosphino)ethane]palladium(0) in dichloromethane T=60 - 65°C; 17 h;
参考文献
Li, Pei; Alper, Howard
Journal of Organic Chemistry, 1986 , vol. 51, # 23 p. 4354 - 4356
反应条件
in N,N-dimethyl-formamide T=150°C; 12 h; Inert atmosphere; Overall yield = 72 percent;
参考文献
COUNCIL OF SCIENTIFIC and INDUSTRIAL RESEARCH; AHUJA, Brij, Bhushan; REKULA, Reddy, Santosh; SUDALAI, Arumugam
Patent: WO2013/132520 A1, 2013 ;
Location in patent: Page/Page column 8; 9 ;
反应条件
1: caesium carbonate; tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane / 1,4-dioxane; water / 65 °C / |Inert atmosphere 2: bis-triphenylphosphine-palladium(II) chloride; sodium tetrahydroborate; N,N,N',N,-tetramethylethylenediamine / tetrahydrofuran / 5 h / 25 °C / |Inert atmosphere View Scheme
参考文献
Chelucci, Giorgio
Chemical Communications, 2014 , vol. 50, # 31 p. 4069 - 4072
反应条件
1: caesium carbonate; tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane / 1,4-dioxane; water / 65 °C / |Inert atmosphere 2: bis-triphenylphosphine-palladium(II) chloride; sodium tetrahydroborate; N,N,N',N,-tetramethylethylenediamine / tetrahydrofuran / 5 h / 25 °C / |Inert atmosphere View Scheme
参考文献
Chelucci, Giorgio
Chemical Communications, 2014 , vol. 50, # 31 p. 4069 - 4072
反应条件
caesium carbonate; dimethyl sulfoxide T=115°C; 12 h;
参考文献
Zhao, Ming; Kuang, Chunxiang; Yang, Qing; Cheng, Xuezhi
Tetrahedron Letters, 2011 , vol. 52, # 9 p. 992 - 994
反应条件
iodide; magnesium in tetrahydrofuran Heating; Yield given;
参考文献
Hijfte, Luc Van; Kolb, Michael; Witz, Pascale
Tetrahedron Letters, 1989 , vol. 30, # 28 p. 3655 - 3656
反应条件
dimethyl benzene-1,4-dicarboxylate; tetra-n-butylammonium tetrafluoroborate in N,N-dimethyl-formamide effect of proton donors; indirect electrochemical reduction of vinyl halides and related compounds; Product distribution;
参考文献
Gatti, Norberto; Jugelt, Werner; Lund, Henning
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1987 , vol. 41, # 9 p. 646 - 652
