3,5,5-三甲基-4-(3-氧代丁基)环己-2-烯-1-酮合成路线 （共 5 条）
反应条件
1: 90 percent / H2 / Raney nickel
2: 80 percent / benzene
3: (t-BuO)2CrO2, acetic anhydride / CCl4 / 24 h / 70 °C
4: aq. acid / acetone / Ambient temperature
View Scheme
参考文献
Koenst, W.M.B.; Apeldoorn, W.; Boelens, H.
Synthetic Communications, 1980 , vol. 10, # 12 p. 899 - 904
反应条件
aq. acid in acetone
Ambient temperature; Yield given;
参考文献
Koenst, W.M.B.; Apeldoorn, W.; Boelens, H.
Synthetic Communications, 1980 , vol. 10, # 12 p. 899 - 904
反应条件
1: (t-BuO)2CrO2, acetic anhydride / CCl4 / 24 h / 70 °C
2: aq. acid / acetone / Ambient temperature
View Scheme
参考文献
Koenst, W.M.B.; Apeldoorn, W.; Boelens, H.
Synthetic Communications, 1980 , vol. 10, # 12 p. 899 - 904
反应条件
1: 80 percent / benzene
2: (t-BuO)2CrO2, acetic anhydride / CCl4 / 24 h / 70 °C
3: aq. acid / acetone / Ambient temperature
View Scheme
参考文献
Koenst, W.M.B.; Apeldoorn, W.; Boelens, H.
Synthetic Communications, 1980 , vol. 10, # 12 p. 899 - 904
反应条件
1: 30 percent / MeMgBr, FeCl3 / diethyl ether / 1.) 0 deg C, 15 min; 0 deg C, 30 min, 2.) 0 deg C, 1 h; r.t., 1 h
2: 84 percent / aq. HCl / tetrahydrofuran / 1 h / 25 °C
View Scheme
参考文献
Ito, Nobuhiko; Etoh, Takeaki
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 19 p. 2397 - 2405
