1: KOH-solution / -10 °C 2: alkaline permanganate View Scheme

potassium hydroxide T=-10°C;

bis-[(trifluoroacetoxy)iodo]benzene in tetrahydrofuran T=20°C; 6 h;

hydrogenchloride; tin(ll) chloride

hydrogenchloride; amalgamated zinc; ethanol

sodium tetrahydroborate; tin(IV) chloride 1.) CH2Cl2, nitromethane, -20 deg C, 10 min; 2.) methanol, -20 deg C, 10 min; Multistep reaction;

暂无反应条件数据

1: 1.) oxalyl chloride / 1.) benzene, reflux, 9 h, 2.) pyridine, N,N-dimethylaminopyridine, r.t., 48 h 2: 1.73 g / CH3COOH, H2 / 10percent Pd/C / ethyl acetate / 760 Torr 3: 840 mg / DMAP / pyridine / Ambient temperature 4: NBS / CCl4 / 1.5 h / Heating 5: acetonitrile / Heating; overnight 6: Et3N / toluene / 16 h / Heating 7: LiAlH4 / tetrahydrofuran / 8 h View Scheme

iron(III) chloride