(2,2-二甲基丙基)锂合成路线 （共 17 条）
反应条件
1: (i) Et2O, (ii) /BRN= 473192/
2: aq. NaOH / dioxane
View Scheme
参考文献
Bartlett,P.D.; Tidwell,T.T.
Journal of the American Chemical Society, 1968 , vol. 90, p. 4421 - 4428
参考文献
Watanabe, Hamao; Inose, Jun; Fukushima, Koji; Kougo, Yuichi; Nagai, Yoichiro
Chemistry Letters, 1983 , p. 1711 - 1714
反应条件
in diethyl ether
at 40°C for 5 h;
参考文献
Taoufik, Mostafa; Cordonnier, Marie-Anne; Santini, Catherine C.; Basset, Jean-Marie; Candy, Jean-Pierre
New Journal of Chemistry, 2004 , vol. 28, # 12 p. 1531 - 1537
反应条件
in hexane
Addn. of neopentyllithium to a suspn. of AlBr3 in hexane at 0°C in 20 min under protective gas, refluxing (3 h).; Vac. distn. of hexane, sepn. of Al-compd. from LiBr by flask to flask vac. distn. at 120°C. Short-path vac. distn., elem. anal., mol wt.;
参考文献
Beachley, O. T. Jr.; Victoriano, L.
Organometallics, 1988 , vol. 7, p. 63 - 67
反应条件
in hexane
byproducts: LiCl; Ar-atmosphere; addn. of LiCH2CMe3 to AlCl3 suspn. (during 1 h, 0°C), refluxing (36 h); evapn. (vac.), distn. (vac.);
参考文献
Schram, Eugene P.; Sudha, Narasimhan
Inorganica Chimica Acta, 1991 , vol. 183, p. 213 - 216
反应条件
in tetrahydrofuran; diethyl ether; pentane
参考文献
Negishi, Ei-ichi; Swanson, Douglas R.; Rousset, Christophe J.
Journal of Organic Chemistry, 1990 , vol. 55, # 19 p. 5406 - 5409
参考文献
Wochner, Franz; Brintzinger, Hans H.
Journal of Organometallic Chemistry, 1986 , vol. 309, p. 65 - 76
