甲基 6-溴-6-脱氧-alpha-D-吡喃葡萄糖苷 2,3,4-三乙酸酯合成路线 （共 4 条）
反应条件
pyridine
24 h; Ambient temperature;
参考文献
Berberan-Santos, Mario N.; Canceill, Josette; Brochon, Jean-Claude; Jullien, Ludovic; Lehn, Jean-Marie; Pouget, Jacques; Tauc, Patrick; Valeur, Bernard
Journal of the American Chemical Society, 1992 , vol. 114, # 16 p. 6427 - 6436
反应条件
1: 1.) methanesulfonyl bromide, 2.) sodium methoxide / 1.) DMF, 65 deg C, 19 h, 2.) MeOH
2: 77 percent / pyridine / 24 h / Ambient temperature
View Scheme
参考文献
Berberan-Santos, Mario N.; Canceill, Josette; Brochon, Jean-Claude; Jullien, Ludovic; Lehn, Jean-Marie; Pouget, Jacques; Tauc, Patrick; Valeur, Bernard
Journal of the American Chemical Society, 1992 , vol. 114, # 16 p. 6427 - 6436
反应条件
[NO][PF6]; tetraethylammonium bromide
1.) CH3CN, 0 deg C, 5 min, 2.) 0 deg C, 1 h; Yield given. Multistep reaction;
参考文献
Jacobsen, Steffen
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1984 , vol. 38, # 2 p. 157 - 164
参考文献
Helferich et al.
Chemische Berichte, 1926 , vol. 59, p. 79,83
