3,4-二甲基-1-戊烯合成路线 (共 11 条)
反应条件
dodecacarbonyltetrarhodium(0); hydrogen in benzene T=20°C; P=76005.1 Torr; Autoclave; regioselective reaction;
参考文献
Lazzaroni, Raffaello; Settambolo, Roberta; Alagona, Giuliano; Ghio, Caterina
Journal of Molecular Catalysis A: Chemical, 2012 , vol. 356, p. 1 - 13
反应条件
dicationic Pt(II) ethylene complex 1 tetrafluoroborate salt in nitromethane
T=20°C; 7 h;
参考文献
Hahn, Christine; Cucciolito, Maria E.; Vitagliano, Aldo
Journal of the American Chemical Society, 2002 , vol. 124, # 31 p. 9038 - 9039
反应条件
ethene in nitromethane
stirring a soln. of platinum complex with alkyne in nitromethane at 20°C under 1 atm of ethylene for 7 h; evapn.;
参考文献
Hahn, Christine; Cucciolito, Maria E.; Vitagliano, Aldo
Journal of the American Chemical Society, 2002 , vol. 124, # 31 p. 9038 - 9039
反应条件
2BF4(1-)*C31H35N5Pt(2+) in dichloromethane-d2
T=100°C; P=3750.38 Torr; 192 h; Inert atmosphere;
参考文献
Serra, Daniel; Cao, Peng; Cabrera, Jose; Padilla, Robin; Rominger, Frank; Limbach, Michael
Organometallics, 2011 , vol. 30, # 7 p. 1885 - 1895
反应条件
1: aq. HCl, CaCl2, CuCl / Cu
2: Zn-Cu
3: H2 / Pd-BaSO4
View Scheme
参考文献
Crombie,L. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1975 , p. 1081 - 1090
反应条件
1: Zn-Cu
2: H2 / Pd-BaSO4
View Scheme
参考文献
Crombie,L. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1975 , p. 1081 - 1090
反应条件
(i) , (ii) /BRN= 1719963/, Et2O; Multistep reaction;
参考文献
Sassiver,M.L.; English,J.
Journal of the American Chemical Society, 1960 , vol. 82, p. 4891 - 4895
反应条件
hydrogen; palladium on barium sulfate
参考文献
Crombie,L. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1975 , p. 1081 - 1090
反应条件
platinum
T=389.9°C; selectivity of transformation, ratios of the aromatization in He or H2 carrier gas and ratios of the transformation to trans/cis isomers in hydrogen carrier gas at other temperature; Product distribution;
参考文献
Zimmer, H.; Paal, Z.; Tetenyi, P.
Acta Chimica Academiae Scientiarum Hungaricae, 1982 , vol. 111, # 4 p. 513 - 532
反应条件
das Stearat liefert bei der Pyrolyse;
参考文献
Keulemans; Kwantes; van Bavel
Recueil des Travaux Chimiques des Pays-Bas, 1948 , vol. 67, p. 302