9-(三甲基甲硅烷基)芴合成路线 （共 37 条）
反应条件
1: 1.) n-BuLi / 1.) THF
2: 94 percent / Li, NH3, t-BuOH / tetrahydrofuran / 0.5 h / -78 °C
3: 90 percent / 1.0 M tetrabutylammonium fluoride (TBAF) / tetrahydrofuran
View Scheme
参考文献
Smith, W. Kimmer; Hardin, Julie N.; Rabideau, Peter W.
Journal of Organic Chemistry, 1990 , vol. 55, # 18 p. 5301 - 5302
反应条件
in isopropyl alcohol
T=50°C; Rate constant;
参考文献
Eaborn, Colin; Mahmoud, Foad M.S.
Journal of Organometallic Chemistry, 1981 , vol. 206, # 1 p. 49 - 58
反应条件
benzanthrene lithium salt in tetrahydrofuran
T=25°C; also with 9-benzylbenzo<def>fluorene lithium salt; free ion acidity; Equilibrium constant;
参考文献
Streitwieser, Andrew; Xie, Linfeng; Wang, Peng; Bachrach, Steven M.
Journal of Organic Chemistry, 1993 , vol. 58, p. 1778 - 1784
反应条件
n-butyllithium in tetrahydrofuran; hexane
4 h; Ambient temperature;
参考文献
Porskamp, P. A. T. W.; Leij, M. van der; Lammerink, B. H. M.; Zwanenburg, B.
Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 9 p. 400 - 404
反应条件
1: (9H-fluoren-9-yl)trimethylsilane With n-butyllithium in tetrahydrofuran; hexane
T=-78 - 0°C;
2: 1,1-di(p-methoxyphenyl)-ketone in tetrahydrofuran; hexane
T=20°C; Peterson olefination; 12 h; Further stages.;
参考文献
Mills, Nancy S.; Benish, Michele A.; Ybarra, Christie
Journal of Organic Chemistry, 2002 , vol. 67, # 7 p. 2003 - 2012
反应条件
n-butyllithium in tetrahydrofuran; hexane
4 h; Ambient temperature;
参考文献
Porskamp, P. A. T. W.; Leij, M. van der; Lammerink, B. H. M.; Zwanenburg, B.
Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 9 p. 400 - 404
反应条件
1: NBS, (PhCO)2O2 / CCl4
2: Ag2SO4 / H2O; acetone
3: Py / diethyl ether
View Scheme
参考文献
Reetz,M.T. et al.
Chemische Berichte, 1976 , vol. 109, p. 2716 - 2727
